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In Hollywood, there are the rebellious ones, and then there are the squeaky clean goodie two shoes, but do we ever really know who’s who? 

We know that stars do need to let off some steam every once in awhile and party it up, but a night out can make or break a career when it comes to the world of glitz and glam.

Reese Witherspoon, one of Hollywood’s sweetest, acted out of order with a cop while her husband Jim Toth was catching a DUI, leading to her arrest this past week. 

PHOTOS: One Too Many Drinks! Reese Witherspoon & Husband Arrested 

It was definitely surprising for most of us who are used to the smiley actress we all know and love on our movie screens. What about Legally Blonde, Reese?!

But Reese is not the only sweetheart who has surprisingly switched up their image by getting arrested.

DETAILS: Terrorism Trend? Chicago Teen Arrested For Alleged Al Qaeda Link

Check out the list of sweethearts who turned bad below!

1. Khloe Kardashian-Odom

Khloe shocked the world when she was arrested in March 2007 for driving under the influence. She was shooting her family reality TV show Keeping Up with the Kardashians at the time of her arrest. Khlo served just three days of her month-long jail sentence, but we’re pretty sure she learned her lesson.

2. Bruno Mars

In 2012, the “When I Was Your Man” singer made headlines for something other than his soulful voice. He was arrested in Las Vegas for possession of cocaine. The pop star then lied to police, telling them it was his first time using drugs; he later admitted he was heavily intoxicated at the time of his arrest. Damn, Bruno.

3. Amanda Bynes

Amanda Bynes stole our hearts when she first appeared in the hilarious ’90s Nickelodeon sketch comedy show All That. But in April 2012, Bynes was arrested for DUI. Since then, it’s been nothing but trouble for the 27-year-old retired actress. 

4. Paul Reubens

Paul Reubens, aka Pee Wee Herman, shocked parents and children everywhere when he was arrested. In November 2002, Reubens turned himself in to police after being charged with possession of kiddie porn. Gross, right? It gets worse. The Pee-Wee’s Playhouse star had previously been arrested and charged with indecent exposure in 1991. 

5. Kevin Hart

Sweet funny-man Kevin Hart was certainly not laughing when he was arrested earlier this month for driving under the influence. The 32-year-old comedian and actor was stopped after police spotted him driving erratically, doing 90 miles per hour, and nearly colliding with a gas tanker. Hart admitted to police he had been drinking and later said the arrest was a “wake up call.” 

6. Lindsay Lohan

Lindsay Lohan is used to negative media attention by now, however, fans were shocked to learn of her first arrest in 2007. Lindsay was charged with driving under the influence and possession of cocaine after losing control of her car in Beverly Hills. This was the first of many arrests the young actress would rack up.

7. Ne-Yo

R&B singer Ne-Yo made waves in the media when he was arrested in 2008 for driving recklessly without a license. He was not under the influence of any drugs or alcohol at the time.

8. Haley Joel Osment

Haley Joel Osment made his way into our hearts as the adorable youngster who saw dead people in The Sixth Sense. He resurfaced seven years later when he was arrested after losing control of his vehicle. Osment was charged with driving under the influence and driving under the age of 21 with a blood alcohol level of .05 or higher; he was 18 at the time.

9. Paris Hilton

Paris Hilton became a household name after she and then-best friend Nicole Richie made their reality TV debut on The Simple Life. Shortly after, Paris fell victim to the fame monster and found herself in all sorts of trouble, starting with an arrest for possession of cocaine.

10. Mischa Barton

California girl Mischa Barton broke our hearts as she went from TV good girl Marissa Cooper on The O.C. to real life criminal. Barton was arrested in 2007 for DUI, drug possession charges and driving without a license.